JEE Main · Chemistry · Aldehydes, Ketones and Carboxylic Acids
Grignard Reagent Addition
JEE Main asked Grignard Reagent Addition 7 times in 7 of the 108 shifts Lumi analysed, in 2020, 2021, 2022 and 2023. It belongs to Nucleophilic Addition, in Aldehydes, Ketones and Carboxylic Acids (Chemistry). The longest wait between two years asking it was 1 year. In 2021 and 2022 it came in more than one shift of the same year.
Updated 2026-10-24
- Times asked
- 7
- in 7 shifts
- Years
- 4 of 8
- First asked
- 2020
- last in 2023
- Pattern
- Comes in cycles
- across the analysed shifts
Questions on this idea a shift, by year
2017–2026. Asked in 2020, 2021, 2022 and 2023. Years differ in how many shifts Lumi analysed, so each year is scaled to one shift of 25 Chemistry questions.
Raw count: 2017: 0 in 1 shift · 2020: 1 in 12 shifts · 2021: 3 in 24 shifts · 2022: 2 in 24 shifts · 2023: 1 in 12 shifts · 2024: 0 in 18 shifts · 2025: 0 in 8 shifts · 2026: 0 in 9 shifts.
Shift by shift
Each square is one analysed shift, in date order. Open a filled one for that paper.
How JEE Main framed it
Diagram based is the usual form. Skill tested: multi-step.
- Predict product of reaction
- Grignard from bromoketone then hydrolysis
Difficulty
Every question was multiple choice.
Every question
All 7 questions
From the official JEE Main shift papers, newest first. Open one for the full question, the options and the official answer.
- 12 Apr 2023, Shift 1 · Q76In the following reaction [figure: CH3-C(=O)-CH2-CH(CH3)-Br, (i) Mg (ii) -> 'A' (Major Product)] A isHardSingle correctHas a figure
- 26 Jun 2022, Shift 1 · Q75[figure: drawn structure with the label MgBr at its upper end and the label MgBr at its lower end, the two joined by a bracket-shaped…HardOtherHas a figure
- 25 Jun 2022, Shift 2 · Q76In the given reaction [drawn…MediumDiagram basedHas a figure
- 25 Jul 2021, Shift 2 · Q50A reaction of benzonitrile with one equivalent followed by hydrolysis produces a yellow liquid "P". The compound "P"…MediumSingle correct
- 27 Aug 2021, Shift 2 · Q44Which one of the following is the major product of the given reaction ? [reaction drawn: a fused bicyclic compound - a benzene ring (drawn…HardDiagram basedHas a figure
- 4 Aug 2021, Shift 2 · Q44The major products A and B in the following reaction sequence are [reaction scheme: see figure_note] (Ph = - )MediumDiagram basedHas a figure
- 9 Jan 2020, Shift 1 · Q45Identify (A) in the following reaction sequence : (A) Gives Positive iodoform test…HardDiagram basedHas a figure
Shifts: 9 Jan 2020, Shift 1, 25 Jul 2021, Shift 2, 4 Aug 2021, Shift 2, 27 Aug 2021, Shift 2, 25 Jun 2022, Shift 2, 26 Jun 2022, Shift 1, 12 Apr 2023, Shift 1.
Same topic
Other ideas in Nucleophilic Addition
Nucleophilic Addition has 20 ideas JEE Main has asked; 6 of them came up in more than one question. The 12 most asked are below.
- Aldehyde vs Ketone Reactivity3× · 2024
- 2,4-DNP (Brady's Reagent) Test2× · 2025
- Cyanohydrin Formation2× · 2024
- Grignard Addition to Alpha,Beta-Unsaturated Carbonyls2× · 2023
- Reduction of Cyanohydrins2× · 2021
- Acetal Hydrolysis Conditionsonce · 2026
- Semicarbazide Regioselectivityonce · 2026
- Grignard Enolization Competitiononce · 2024
- Regioselectivity in Semicarbazideonce · 2024
- Stability of Chloral Hydrateonce · 2023
- 1,2- vs 1,4-Addition to Conjugated Carbonylsonce · 2022
- Enamine Formationonce · 2022