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Saturday, 31 October

JEE Main 2021 · ChemistryMultiple choiceDiagram basedMediumApplication

JEE Main 26 August 2021, Shift 2, Chemistry Q44

Question 44 of 90 in this shift, Chemistry question 14 of 30, Section A.

[reaction scheme] drawn structure --(Br2\mathrm{Br_2} / AlBr3\mathrm{AlBr_3} (C2H5)2O(\mathrm{C_2H_5})_2\mathrm{O})--> ‘A’ (Major Product) Consider the given reaction, the Product A\mathbf{A} is :

The figure, in words

Reactant drawn: benzene ring bonded to a C=O carbon (O drawn above), which continues into a four-carbon zigzag chain; arrow labelled Br2 above, AlBr3 (C2H5)2O below; product labelled 'A' (Major Product).
  1. (1)[figure: benzene ring bearing a C=O group, the carbonyl carbon continuing into a four-carbon zigzag chain; a Br is attached to the ring at the ring position two bonds away from the carbonyl-bearing carbon (meta-type position as drawn, below the ring)]Official answer
  2. (2)[figure: benzene ring bearing a C=O group, the carbonyl carbon continuing into a four-carbon zigzag chain; Br is attached to the last (terminal) carbon of the chain]
  3. (3)[figure: benzene ring bearing a C=O group, the carbonyl carbon continuing into a four-carbon zigzag chain; Br is attached to the third carbon after the carbonyl carbon, the carbon next to the terminal carbon]
  4. (4)[figure: benzene ring bearing a C=O group, the carbonyl carbon continuing into a four-carbon zigzag chain; Br is attached to the ring at the position opposite (para, lower left) to the carbonyl-bearing carbon]

Official answer

Option 1

NTA final key.

Same idea in other shifts

Asked 11× in all
  1. 2 Apr 2026, Shift 1 · Q66For the given molecule, "xx", the preferred site for the attack of the electrophile is :MediumDiagram basedHas a figure
  2. 8 Apr 2025, Shift 2 · Q66Choose the correct set of reagents for the following conversion. Ethyl benzene → [structure: p-bromostyrene, i.e. benzene ring with CH=CH2…MediumSingle correctHas a figure
  3. 1 Feb 2024, Shift 1 · Q88Total number of deactivating groups in aromatic electrophilic substitution reaction among the following is ________.…MediumNumerical valueHas a figure
  4. 1 Feb 2024, Shift 2 · Q74The set of meta directing functional groups from the following sets is :EasySingle correct
  5. 27 Jan 2024, Shift 1 · Q88Among the following, total number of meta directing functional groups is __________. (Integer based)…EasyNumerical value
  6. 24 Jun 2022, Shift 1 · Q73In the given reaction sequence, the major product 'C' is :…MediumSingle correctHas a figure
  7. 26 Jun 2022, Shift 2 · Q74Halogenation of which one of the following will yield m-substituted product with respect to methyl group as a major product?MediumSingle correctHas a figure
  8. 26 Aug 2021, Shift 1 · Q46The correct options for the products A and B of the following reactions are : [figure: hexagonal ring (inner circle) with OH at top; left…MediumDiagram basedHas a figure

Question text from the official JEE Main paper published by NTA; answer from the final answer key. Chapter, topic and idea tags, difficulty and skill are Lumi’s. This question needs a figure we do not reproduce; it is described in words above. Lumi analyses 108 of the 174 JEE Main shifts held from 2017 to 2026.